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Article Details


Glycosylated Metal Phthalocyanines

[ Vol. 11 , Issue. 1 ]

Author(s):

Michael Hanack, Goran Crucius, Mário J.F. Calvete and Thomas Ziegler   Pages 59 - 66 ( 8 )

Abstract:


Methods for the synthesis of mono-, di-, and tetra-glycosylated phthalonitriles are described, which are key building blocks for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. Than the preparation of symmetrically and unsymmetrically tetra- and octa-glycosylated zinc phthalocyanines in which the carbohydrate is attached either anomerically or via another one of its OH-groups to the phthalocyanine macrocycle is assessed.

Keywords:

Glycosylation, phthalocyanine, phthalonitrile.

Affiliation:

Institut fur Organische Chemie der Universitat Tubingen, Auf der Morgenstelle 18, 72076 Tubingen, Germany.



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