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Synthesis of Asymmetric Diaryl Sulfides by SNAr Reaction of Substituted Nitrobenzene with Aryl Disulfides

[ Vol. 10 , Issue. 6 ]

Author(s):

Naoki Enjo, Rong Lu and Tetsuo Miyakoshi   Pages 961 - 968 ( 8 )

Abstract:


A series of sulfides was successfully synthesized from nitroarenes by SNAr reaction via elimination of a nitro or phenylsulfonyl group. The SNAr reaction mechanism is found to depend on the position and type of substituents, and the effect of two-electron withdrawing groups was also examined.

Keywords:

Sulfide, SNAr reaction, nitro group, aryl disulfide.

Affiliation:

Department of Applied Chemistry, School of Science and Technology, Meiji University, 1-1-1 Higashi-mita, Tama-ku, Kawasaki-shi, 214-8571, Japan.



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