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Oxazolidine- and Oxazoline-2-thiones: An Update

[ Vol. 14 , Issue. 8 ]

Author(s):

Estibaliz Sansinenea*, Aurelio Ortiz, Patrick Rollin and Sandrina Silva*   Pages 1109 - 1131 ( 23 )

Abstract:


Background: Sulfur-containing compounds are widespread among natural products and bioactive substances, and also useful ligands in asymmetric catalysis.

Objectives: In this context, different methods for the preparation of oxazolidine- and oxazoline-2-thiones and their more recent applications are reviewed.

Conclusions: In this survey, novel rearrangements and new reactions have also been summarized since 2007 until 2016.

Keywords:

Oxazolidine-2-thiones, oxazoline-2-thiones, chiral auxiliary, applications, asymmetric synthesis, diastereoselectivity.

Affiliation:

Facultad de Ciencias Quimicas de la Benemerita Universidad Autonoma de Puebla, Puebla Pue., 72570, Facultad de Ciencias Quimicas de la Benemerita Universidad Autonoma de Puebla, Puebla Pue., 72570, Universite d'Orleans et CNRS, ICOA, UMR 7311, BP 6759, F-45067 Orleans, Department of Chemistry, Federal University of Sao Carlos, Sao Paulo 13565-905

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