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Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation

[ Vol. 18 , Issue. 5 ]

Author(s):

Yangyang Ma, Jiayun Li*, Ying Bai and Jiajian Peng*   Pages 425 - 430 ( 6 )

Abstract:


A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.

Keywords:

Cobalt complex, N, P-Ligands, hydrosilylation, alkene, KOtBu, facile.

Affiliation:

Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121

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