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Recent Advances in Metal-Catalyzed Heterocyclic C-P Bond Formation


Feng Xu* and Yu Hui   Pages 1 - 11 ( 11 )


The Phosphorus-containing heterocycles are an important class of compounds in organic chemistry. Because of their potential application in many fields, especially the synthetic pesticides, medicine and catalyst, the Phosphorus-containing heterocycles have attracted continuous attention by organic synthesis scientists. The development of efficient and low-cost catalytic systems is great interest for construction heterocycles C–P bond. Usually, the Phosphorus-containing heterocycles is prepared via direct carbon–hydrogen (C–H) bond activation or pre-functionalized of heterocycles with carbon–hydrogen ( P-H) bond of phosphorus compounds reaction by metal-catalyzed. This review summarizes recent progress in the heterocycles C-P bond formation reactions by metal-catalyzed, which mainly focusing on the discussion of the reaction mechanism. Aims to provide efficient methods for the future synthesis and application in this field.


Phosphorus-containing heterocycles, metal-catalyzed, C-P bond, cross-coupling reaction, C-H bond activation, radical addition


School of Mathematics and Information Science, Guiyang University, Guiyang 550005,China,Jianlongdong 103 Road, Nanming District, Guiyang city, Guizhou province, Chaotic Matter Science Research Center, Jiangxi University of Science and Technology Nanchang campus,Nanchang 330013

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