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SELENIUM AS A VERSATILE REAGENT IN ORGANIC SYNTHESIS: MORE THAN ALLYLIC OXIDATION

Author(s):

Samuel Thurow*, Laura Abenante, João Marcos Anghinoni and Eder João Lenardão*  

Abstract:


For many years since its discovery, Selenium has played the role of a bad boy who became a hero in organic transformations. Selenium dioxide, for instance, is one of the most remembered reagents in allylic oxidations, having been applied in the synthesis of several naturally occurring products. The main goal of this review is to show the recent advances in the use of classical and new selenium reagents in organic synthesis. As demonstrated through around 60 references discussed in this study, selenium can go even forward as a versatile reagent. We bring a collection of selenium reagents and their transformations that are still hidden from most synthetic organic chemists.

Keywords:

Selenium; organochalcogen; catalysis; redox; functionalization; selenium dioxide

Affiliation:

Institute of Chemistry, State University of Campinas, Rua Monteiro Lobato, 270, 13083-862, Campinas, SP, Laboratório de Síntese Orgânica Limpa – LASOL, CCQFA. Universidade Federal de Pelotas – UFPel, P. O. Box 354, 96010-900, Pelotas, RS, Laboratório de Síntese Orgânica Limpa – LASOL, CCQFA. Universidade Federal de Pelotas – UFPel, P. O. Box 354, 96010-900, Pelotas, RS, Laboratório de Síntese Orgânica Limpa – LASOL, CCQFA. Universidade Federal de Pelotas – UFPel, P. O. Box 354, 96010-900, Pelotas, RS



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