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Strategies of Synthetic Methodologies for Constructing β-Mannosidic Linkage

[ Vol. 2 , Issue. 2 ]

Author(s):

E. S. H. El Ashry, N. Rashed and E. S. I. Ibrahim   Pages 175 - 213 ( 39 )

Abstract:


The various synthetic methodologies for constructing the β-mannosidic bonds have been reviewed. Different strategies are covered such as inter and intramolecular glycosidation methods as well as epimerization of β-glucosides, reductive cleavage of anomeric orthoesters, radical anomeric inversion, enzymatic synthesis and mannosides from non-carbohydrate.

Keywords:

glycosyl acceptors, mannosyl donor, aglycon delivery, epimerization, b-mannopyranosides, stereoselective mannosidation, 1,2-cis-mannosides, benzylsulfonyl

Affiliation:

Alexandria University, Alexandria, Egypt.



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