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Palladium-Catalyzed Allylic Substitution Reaction in Polymer Synthesis

[ Vol. 2 , Issue. 1 ]

Author(s):

N. Nomura, K. Tsurugi, N. Yoshida and M. Okada   Pages 21 - 38 ( 18 )

Abstract:


Polymer synthesis via the palladium-catalyzed allylic substitution reaction between allylic esters and malonic esters, namely the Tsuji-Trost reaction, is summarized in this review. Due to the versatility and potential of the Tsuji-Trost reaction, four polymerization patterns for various functionalized polymers have been reported.

Keywords:

tsuji-trost reaction, allylpalladium, polymerization, allylation, palladium, polymer synthesis

Affiliation:

Laboratory of Polymer Chemistry, Graduate School of Bioagricultural Sciences, Nagoya University, Nagoya 464-8601, Japan.



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