D. Savoia and A. Gualandi Pages 102 - 118 ( 17 )
Chiral non-racemic perazamacrocyles containing three or more nitrogen atoms in the form of different functions (amine, amide, imine) are prepared from optically active amines, diamines, α-aminoacids, and their derivatives, by properly selected methodologies. The many applications of these optically pure perazamacrocycles rely on the basic and/or hydrogen bond donor properties of the nitrogen functions and include metal ions coordination, supramolecular chemistry, material science, molecular and enantioselective recognition, and asymmetric catalysis.
Amines, asymmetric catalysis, chiral perazamacrocycles, cyclization, enantioselective recognition, metal complexes, porphyrins, supramolecular chemistry
Dipartimento di Chimica “G. Ciamician”, Universita di Bologna, via Selmi 2, 40126 Bologna, Italy.