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Chiral Perazamacrocycles: Synthesis and Applications. Part 1

[ Vol. 6 , Issue. 2 ]

Author(s):

D. Savoia and A. Gualandi   Pages 102 - 118 ( 17 )

Abstract:


Chiral non-racemic perazamacrocyles containing three or more nitrogen atoms in the form of different functions (amine, amide, imine) are prepared from optically active amines, diamines, α-aminoacids, and their derivatives, by properly selected methodologies. The many applications of these optically pure perazamacrocycles rely on the basic and/or hydrogen bond donor properties of the nitrogen functions and include metal ions coordination, supramolecular chemistry, material science, molecular and enantioselective recognition, and asymmetric catalysis.

Keywords:

Amines, asymmetric catalysis, chiral perazamacrocycles, cyclization, enantioselective recognition, metal complexes, porphyrins, supramolecular chemistry

Affiliation:

Dipartimento di Chimica “G. Ciamician”, Universita di Bologna, via Selmi 2, 40126 Bologna, Italy.



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