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Bifunctional Chiral Organocatalysts in Organic Transformations

[ Vol. 6 , Issue. 4 ]

Author(s):

Pinaki S. Bhadury, Bao-An Song, Song Yang, De-Yu Hu and Wei Xue   Pages 380 - 399 ( 20 )

Abstract:


In continuation to our earlier review, we report herein further development on the organocatalytic approach for the synthesis of enantioenriched organic compounds. Application of synthetic bifunctional chiral organocatalysts with emphasis on Brønsted acid catalyst derived from chiral phosphoric acid derivative, and mechanism of asymmetric catalysis are discussed.

Keywords:

Asymmetric organocatalysis, axially chiral binaphthyl, Bronsted acid catalyst, chiral thiourea, absolute configuration, synthesis

Affiliation:

Center for Research and Development of Fine Chemicals, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, P. R. China.



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